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Pd promoted Mo/Al 2 O 3 sulfide catalysts were tested in hydrodesulfurization (HDS) of thiophene and benzothiophene in the presence of different amounts of basic nitrogen compounds (pyridine, quinoline) and compared with CoMo/Al 2 O 3 . The Pd promoted catalysts were in both HDS reactions more nitrogen tolerant than CoMo/Al 2 O 3 . In thiophene HDS in...
Rh and Ru promoted Mo/Al2O3 catalysts were tested in HDS of thiophene in the presence of different amounts of pyridine and compared with CoMo/Al2O3. The Rh and Ru promoted catalysts were more nitrogen tolerant and in the presence of pyridine showed higher HDS activities than CoMo/Al2O3. This was explained by higher C–N bond hydrogenolysis activity and high nitrogen tolerance of the free Rh and Ru...
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