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The exchange reactions of tin diorganohalides R2SnCl2 (R = Et, But, or Ph) with lithium amidophenolate APLi2 (AP is the 4,6-di(tert-butyl)-N-(2,6-diisopropylphenyl)-o-iminobenzo-quinone dianion) in tetrahydrofuran produced the new five-coordinate (Et2SnAP(THF) (3)) and four-coordinate (R2SnAP (R = But, Ph)) tin(IV) complexes. The reaction of Ph2SnCl2 with APLi2 in a nonpolar solvent (hexane or toluene)...
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