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Reaction intermediates have been identified and followed to understand anomalous cracking of jathropha oil triglycerides in the presence of sulphided Co-Mo/Al2O3 catalyst. Undesirable C–C coupling reactions are favoured at temperatures between 320° and 340°C, giving waxy oligomerization products, whereas at temperatures above 340°C, direct hydrocracking of triglycerides to lighter and middle distillates...
Titanosilicates with 3D-wormhole-like mesoporosity were used as support for hydroprocessing catalysts to increase the triglyceride (jatropha oil) deoxygenation and cracking activity of sulfided Ni-Mo and Co-Mo catalysts. Mesoporous titanosilicate supported Co-Mo catalyst showed improved performance in terms of higher yield of kerosene (jet-fuel) range hydrocarbons, 5-times more isomerized product...
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