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Compared with most of the reported logic devices based on the supramolecular approach, systems based on individual molecules can avoid challenging construction requirements. Herein, a novel dioxoporphyrin DPH22 was synthesized and two of its tautomers were characterized by single‐crystal X‐ray diffraction studies. Compound DPH22 exhibits multichannel controllable stepwise tautomerization, protonation,...
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