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We report here an approach toward the synthesis of optically active polyacrylamide bearing amino acid moieties, poly[N-methacryloyl l-leucine methyl ester] (PMALM), with controlled average number molecular weight (M n ) and relatively narrow polydispersity index (PDI, M w /M n <1.3) by atom transfer radical polymerization (ATRP) using initiating system methyl 2-bromopropionate/CuBr/tris(2-dimethylaminoethyl)...
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