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The organic insulator–metal interface is the most important junction in flexible electronics. The strong band offset of organic insulators over the Fermi level of electrodes should theoretically impart a sufficient impediment for charge injection known as the Schottky barrier. However, defect formation through Anderson localization due to topological disorder in polymers leads to reduced barriers...
Nanocoatings
In article number 2101374, Yang Cao, Luyi Sun, and co‐workers present a layered nanocoating comprising hundreds of highly oriented organic/inorganic alternating nanolayers on the polymer surface to revive the Schottky barrier for effective charge‐injection blocking. The superior 2D assembly leads to a flexible material architecture at the electrode–dielectric interface, thus providing...
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