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An experimental study on VOCs removal with photocatalyst in a batch reactor was carried out at atmospheric pressure and room temperature. TiO2 thin film photocatalyst coated on glass spring was prepared with dip-coating method. The photocatalyst was extensively characterized by means of spectroscopy (XRD) and microscopy (SEM). Toluene was taken as the typical VOCs for photocatalytic degradation as...
Optically active molybdenum(VI) dioxo complexes bearing hydrosalen derivatives as ligands were synthesized, grafted on the surface of MCM-41 and MCM-48 and examined as catalysts for asymmetric epoxidation. In case of cis-β-methylstyrene and trans-β-methylstyrene moderate enantiomeric excesses of up to 31% can be reached when the reaction is carried out at room temperature. The catalysts can also be...
Complexes of the type (η 5 -C 5 R 5 )Mo(CO) 3 X (X=Me, Cl; R=H, Me), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined for their catalytic performance at 55°C in systems containing room temperature ionic liquids (RTILs) of composition [BMIM]NTf 2 , [BMIM]PF 6 , [C 8 MIM]PF 6 and [BMIM]BF 4 ...
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