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The synergic effect of zirconium tetrachloride (ZrCl4) on the thermal dehydrogenation of KBH4 has been investigated. Zirconium tetrachloride activated the KBH4 surface during ball milling to improve the dehydrogenation kinetics. The activation energy of dehydrogenation is remarkably reduced to 162 ± 6 kJ/mol as compared to the pure KBH4, which was found to be 274 ± 12 kJ/mol under identical experimental...
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