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In this paper, we summarized our recent studies on the holo-enzyme model in mimicry of coenzyme B12 by cyclodextrin/alkyl(aqua)cobaloxime supramolecular complexes, the [2] and [3] rotaxanes based on cyclodextrin and bisimidazolyl compound, and nano-metal oxide preparation through thermal decomposition of metal acetates with β-cyclodextrin coating.
Conformational analysis of inclusion complexes of sodium 3-hydroxy-2-naphthalenecarboxylate with β-cyclodextrin and heptakis-(2,3,6-tri-o-methyl)-β-cyclodextrin in D2O was investigated by 1D and 2D 1HNMR measurements. The results show that part of the naphthyl group of sodium 3-hydroxy-2-naphthalenecarboxylate is situated in the 2,3-OH side of the β-cyclodextrin cavity asymmetrically while the whole...
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