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A simple example of an isothermal thermodynamic phase diagram for a quaternary system composed of a ternary A–B–C alloy reacting with a single oxidant (O) has been calculated assuming that oxides are insoluble and that they do not interact with each other. The 2D thermodynamic diagrams of the ternary metal–oxygen systems composed of the three types of binary alloys plus the oxidant are reviewed first,...
The effect of a microcrystalline NiAl coating prepared by magnetron sputtering on the high-temperature oxidation resistance of a NiAl–TiC (20 vol.%) composite was investigated in air at 1000 and 1100°C. It was found that the isothermal as well as the cyclic oxidation resistance of the NiAl–TiC composite were greatly improved by the microcrystalline NiAl coating. The oxide scale formed on the NiAl–TiC...
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