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From the deep‐sea‐derived Fusarium sp. ZEN‐48, four known compounds were obtained. Their structures were established by extensive analyses of the NMR, HR‐ESI‐MS, and the X‐ray crystallographic data as brefeldin A (BFA, 1), brevianamide F (2), N‐acetyltryptamine (3), and (+)‐diaporthin (4). Although BFA was extensively investigated for its potent bioactivities, its role on TNFα‐induced necroptosis...