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A bio‐inspired method is used to render controlled wrinkling surface patterns on supramolecular architectures assembled from polyoxometalate (POM) clusters. It involves a polyamine‐multivalent anion interaction generating positively charged coacervates, which while dictating the assembly of POM into spherical structures further facilitate an interesting surface morphogenesis with wrinkling patterns...
Kettenbildung: Durch Poly(L‐lysin) vermittelt organisieren sich Citrat‐funktionalisierte Fe3O4‐Nanopartikel und Hydroxypyrentrisulfonat (HPTS) in Gegenwart von Glutardialdehyd (GA) zu fluoreszierenden, magnetoresponsiven Kügelchen (MFS). Bei Aggregation in Gegenwart eines Permanentmagneten entstehen eindimensionale, magnetische, Perlenketten‐artige Strukturen (siehe Schema).
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