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Dichromate capture: A 3D cationic metal–organic framework consisting of distorted octahedral and tetrahedral cages was constructed by using AgI and 4,4′‐bis(1,2,4‐triazole). The complex exhibits fast exchange, high trapping capacity, and good selectivity for Cr2O72− through single‐crystal to single‐crystal transformation. The complex also features a bluish violet luminescence that is distinctly quenched...
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