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Nano-silica dispersion was generated in situ through the hydrolysis and condensation of tetraethyl orthosilicate with methyl methacrylate and butyl acrylate in micelles as dispersing media, hydrochloric acid as catalyst and methacryloxypropyl trimethoxysilane as modifier. Then, the nano-silica/fluorinated polyacrylate composite latexes were prepared via emulsion polymerization directly using the in...
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