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The mononuclear iron complex 1 was synthesized using a tripodal ligand, tris(2-benzimidazolylmethyl)amine (ntb), where ntb served as a neutral tetradentate chelating ligand for the distorted octahedral ferric ion. Three benzimidazole groups of ntb and one chloride anion formed a base of octahedral geometry. One of the two axial positions was occupied by an apical nitrogen atom of ntb and the other...
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