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The electrochemical polarization and concentration polarization during the discharge of TiNi alloy electrodes are analyzed in terms of a model presented in part I. The ratio of electrochemical polarization to concentration polarization during discharge (η e /η c ) p increases with the number of charge/discharge cycles due to the faster decline in electrocatalytic performance...
The electrochemical properties of TiNi alloy used as an MH electrode were investigated. A mathematical model for the electrochemical discharge capacity of TiNi electrode was developed. The model was used to study the effects of various parameters on the discharge capacity, and cycle life. The predicted results from the model fit well with the experimental results. Increasing the discharge current...
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