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High gravimetric, areal and volumetric capacities together with long lifetime are key indexes for the applications of lithium–sulfur (Li‐S) batteries in compact space. The sulfur host materials play pivotal roles in the practical deployment. Herein, one type of new heterostructure nanosheets composed of cobalt boride (CoB) on nitrogen, boron‐codoped porous carbon (NBC), which is constructed through...