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Polymer-anchored monometallic palladium catalyst PVP-PdCl 2 , (PVP = poly(N-vinyl-2-pyrrolidone)) exhibits very high activity for the hydrogenation of p-chloromitrobenzene (CNB) to aniline (AN) in the presence of base at 65°C and atmospheric pressure. In this case, the substrate is rapidly hydrodechlorinated to nitrobenzene (NB) which is then reduced to AN. Using the polymer-anchored bimetallic...
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