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In this paper we demonstrate an order-of-magnitude suppression of polymerization shrinkage of volume holograms recorded in nanoparticle-polymer composites by green light initiated thiol-ene photopolymerization, as compared to our previously reported nanoparticle-polymer composites with multifunctional (meth)acrylate monomers.
The recording mechanism of a holographic grating in inorganic or organic nanoparticle-polymer composites is described. The diffraction and multiple recording properties of a volume hologram in a nanoparticle-polymer composite film are also described.
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