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We have studied the oxidative addition of halogens (I2 and Br2) and interhalogens (ICl and IBr) on complexes of the type [Pd(thioquinoline)C4(COOMe)4], (thioquinoline=8-(methylthio)quinoline, 8-(t-butylthioquinoline, 2-methyl-8-(methylthio)quinoline, 2-methyl-8-(t-butylthio)quinoline).The expected palladium(thioquinoline)-σ-butadienyl derivatives have been obtained by the stoichiometric addition of...
We have studied from the experimental and theoretical point of view the oxidative addition of halogens (I2 and Br2) and interhalogens (ICl and IBr) on palladiumcyclopentadienyl complexes bearing heteroditopic pyridyl−thioether spectator ligands.Addition of I2 or of a stoichiometric amount of Br2 to a CDCl3 solution of the starting palladacyclopentadienyl complexes yields the expected palladium−σ−butadienyl...
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