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We have investigated the synthesis and physical properties of BiCo221 and BiCo222 compounds intercalated by the iodine. The intercalation of the iodine was successfully performed by the heat treatment at a constant iodine partial pressure. The result of BiCo221 suggests possible substitution of oxygen in Bi–O layer by the iodine. In the case of BiCo222, it was found that the c-axis drastically increased...
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