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Fe3O4@SiO2‐CeCl3 catalyzed chemoselective synthesis of functionalized 3‐substituted‐1,5‐benzodiazepines via one‐pot multicomponent and domino reactions has been developed. During the one‐pot synthesis process, one new cycle and four new bonds (one C–C, two C–N and one C=C) were constructed by the nucleophilic addition and eliminate reaction (dehydration etc.) process, intramolecular proton transfer...
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