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A proposed Nd2Fe14B-core/Nd2(Fe, Co)14B-shell microstructure was realized by diffusion-processing textured Nd14Fe77B9 single-layer film with Nd100−xCox (x=10, 20 and 40) alloys to improve the coercivity thermal stability. The ambient coercivity was increased from around 1T in single-layer film to nearly 2T in diffusion-processed films, which was due to the Nd-rich grain boundaries as seen from transmission...
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