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A facile solvothermal method was adopted to prepare unique hierarchical TiO2 structures which are assembled from single-crystal tubes and inflated with oriented aligned nanoparticles. A F− mediated anisotropic assembling mechanism was proposed based on time dependent experiments and density function theory calculation. Hydrofluoric acid was found to play crucial roles on the nucleation, growth and...
ZnO nanorods consisted of oriented aligned elongated-nanoparticles along the [0001] direction were readily prepared with tunable aspect ratios by a facile solvothermal method. An oriented-attachment growth mechanism was proposed based on time-dependent trails and first principle density function theory calculation. Control experiments indicated that the reaction medium played important roles to influence...
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