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A detailed structural and morphological study on bulk poly(3-hexylthiophene), having high regioregularity (about 98%) and molecular weight of 16kDa, has been performed. The combination of wide- and small-angle X-ray diffraction techniques, for the first time on bulk semicrystalline conjugated polymer, allowed to get insight on the structural features of poly(3-hexylthiophene), subjected to different...
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