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The solution and solid state behavior of the binary system (Cu(II)-N-chloroacetylglycine (Cl-acglyH) and the corresponding ternary systems with 2,2 -bipyridine (bpy) and 1,10-phenanthroline (ophen) were investigated by means of pH-metric and spectrophotometric titrations. The X-ray crystal structure of the complex [Cu(ophen)(Cl-acgly) 2 ] 2H 2 O(Cl-acgly = N-chloroacetylglycine...
The solution and solid state behaviour of the binary system Cu(II)-2-hydroxyhippuric acid (2-OHhipH) and the corresponding ternary system with 2,2'-bipyridine (bpy) were investigated through pH-metric titrations and X-ray crystallography. In solution the species [CuLH -1 ] - and [CubpyL] were found to prevail in the binary and in the ternary system, respectively, both involving...
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