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Optical absorption as well as thermoluminescence emission of LiF:Mg2+ single crystals have been measured before and after exposed to gamma radiation from Co-60 source. Result of DFT calculations for pure bulk LiF indicates a large reduction in band gap energy of the crystal after doping with Mg2+ ions. As impurity concentration of Mg2+ ions in LiF is increased, the activation energy of 225 and 313 nm...
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