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JD5037 (1) is a potent and selective, peripherally acting inverse agonist of the cannabinoid (CB1R) receptor. Peripheral CB1 receptor antagonists/inverse agonists have great potential in the treatment of metabolic disorders like type 2 diabetes, obesity, and nonalcoholic steatohepatitis. We report the synthesis of octadeuterated [2H8]‐JD5037 (S, S) (8) along with its (S, R) diastereomer (13) from...
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