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The organopalladium complex containing ortho-metalated (S)-[1-(dimethylamino)ethyl]naphthalene as the chiral auxiliary has been used as the chiral template to promote the asymmetric cycloaddition reaction between phenyldivinylphosphine and 3,4-dimethyl-1-phenylarsole. The reaction was completed in 1h at room temperature, with the formation of two isomeric cycloadducts in the ratio 1:3. The major phenylvinylphosphino-substituted...
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