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In this study, artificial red blood cells (RBCs) for immobilization of l‐asparaginase are developed. The artificial red blood cells are prepared via a self‐assembly method and characterized by various methods. The prepared material shows a small hydrodynamic size of nearly 120 nm and a zeta potential of ‐7.2 ± 0.2 mV. After l‐asparaginase encapsulation, the particle size is nearly 295 nm and the zeta...