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Intra-crystalline mass transfer in H-ZSM-5 for the entry of n-butylamine, n-butanol, iso-butanol, tert-butanol, n-hexanol, n-octanol, 2,3 dimethyl butane and iso-octane from their bulk liquid phase has been studied by measuring their initial rate of sorption. The entry of the sorbate molecules into the zeolite channels is strongly influenced by the critical size of the molecules, but much more strongly...
The adsorption of methane, ethane, ethylene, and carbon dioxide on silicalite-l and the thermodynamics of adsorption have been investigated under similar conditions using a gravimetric adsorption apparatus. The order for the adsorption of the different adsorbates on silicalite-l is CH 4 < CO 4 < C 2 H 4 ≤ C 2 H 6 . The Dubinin-Polanyi equation...
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