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Semiconductor heterojunctions are used in a wide range of applications including catalysis, sensors, and solar‐to‐chemical energy conversion devices. These materials can spatially separate photogenerated charge across the heterojunction boundary, inhibiting recombination processes and synergistically enhancing their performance beyond the individual components. In this work, the WO3/TiO2 heterojunction...
In article number 1605413, Raul Quesada‐Cabrera, Ivan P. Parkin, and co‐workers synthesize nanostructured WO3/TiO2 heterojunction films. Against common observations, this system shows an unusual electron transfer from WO3 to TiO2, as proven by theoretical and experimental evidence. The advantageous electronic synergy within a high‐surface‐area substrate allows for record high efficiencies for the...
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