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Acetaldehyde oxidation was investigated in a jet-stirred reactor at temperatures from 460 to 900 K, equivalence ratios from 0.5 to 4.0 and pressures of 710–720 Torr. Reactive intermediates under low-temperature conditions, such as methylperoxy, methylhydroperoxide and ketohydroperoxide were detected using synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS). A kinetic model...
Recent experiments on low-temperature oxidation of dimethyl ether (DME) at atmospheric pressure reveal much lower fuel conversion than the predictions of all published models. Consistent with previous measurements, the present work on DME oxidation in a laminar flow reactor between 400 and 1160K at atmospheric pressure also confirmed this behavior. To reduce the gap between model predictions and experimental...
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