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In this study, affinity capillary electrophoresis (ACE) and quantum mechanical density functional theory (DFT) calculations were combined to investigate non‐covalent binding interactions between the hexaarylbenzene‐based receptor (R) and alkali metal ions, Rb+ and Cs+, in methanol. The apparent binding (stability) constants (Kb) of the complexes of receptor R with alkali metal ions in the methanolic...
ACE was applied to the quantitative evaluation of noncovalent binding interactions between benzo‐18‐crown‐6‐ether (B18C6) and several alkali metal ions, Li+, Na+, K+, Rb+ and Cs+, in a mixed binary solvent system, methanol–water (50/50 v/v). The apparent binding (stability) constants (Kb) of B18C6–alkali metal ion complexes in the hydro‐organic medium above were determined from the dependence of the...
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