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In aqueous solution at pH 3.0 and 20 °C, poly(acrylic acid)‐g‐poly(N‐isopropylacrylamide)/monomethoxy poly(ethylene glycol) (PAAc‐g‐PNIPAAm/mPEG) can assemble spontaneously with linear poly(acrylic acid) homopolymers (homoPAAc) into interpolymeric complexes (IPC). The resultant IPC assemblies exhibit a core–corona structure consisting of a hydrophobic PAAc/PNIPAAm complex core surrounded by hydrated...
A facile approach of forming stable polymeric complexes by the two-stage phase transition of the graft copolymer comprising poly(acrylic acid) (PAAc) as the backbone and poly(N-isopropylacrylamide) (PNIPAAm) and monomethoxy poly(ethylene glycol) (mPEG) as the grafts in water was illustrated. Rather loose and hydrated polymeric aggregates with a characteristic hydrophobic multicore structure, achieved...
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