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ICH 2 CH 2 OH decomposes into an oxametallacycle (-CH 2 CH 2 O-) upon its adsorption on oxygen-precovered Cu(100) (O/Cu(100)) at 115 K. -CH 2 CH 2 O- on O/Cu(100) reacts mainly to form C 2 H 4 and CH 3 CHO. ClCH 2 CH 2 OH dissociates on O/Cu(100) to generate ClCH 2 CH 2 O-, instead of -CH 2...
The 1,4-dioxane adsorption and geometry on Cu(100) as functions of coverage and temperature have been studied by temperature-programmed reaction/desorption and reflection-absorption infrared spectroscopy. 1,4-dioxane is adsorbed reversibly on the surface with monolayer desorption at 212 K and multilayer desorption at ~165 K at 4 L exposure. Below ~1.5 L exposure, i.e. 0.6 monolayer coverage, 1,4-dioxane...
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