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Die nickelkatalysierte Fluormethylierung von Arylboronsäuren gelingt mit industriellem Fluormethylbromid (CH2FBr) als Kupplungspartner. X. Zhang et al. berichten in der Zuschrift auf S. 9207 ff. über eine effiziente Methode, die sich auch für das späte Synthesestadium eignet und einen Zugang zu fluormethylierten Produkten mit biologischer Bedeutung öffnet. Im Bild steckt CH2FBr seinen wertvollen CH...
The nickel‐catalyzed fluoromethylation of arylboronic acids was achieved with the industrial raw material fluoromethyl bromide (CH2FBr) as the coupling partner. The reaction proceeded under mild reaction conditions with high efficiency; it features the use of a low‐cost nickel catalyst, synthetic simplicity, and excellent functional‐group compatibility, and provides facile access to fluoromethylated...
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