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Two unprecedented [5+10] icosanuclear molecular 4‐ravels containing four crossings were designed rationally and synthesized successfully using a single‐step strategy as described by Li‐Long Dang, Guo‐Xin Jin et al. in their Research Article (e202301516). This new topology is achieved by utilizing parallel‐displaced π⋅⋅⋅π interactions with carefully selected naphthoquinoyl Cp*M building blocks and...
Die Reaktion von [(DippForm)2Ln(thf)2] mit einem Überschuss an elementaren Schwefel führt in Toluol zur Bildung der dreikernigen Polysulfid‐Koordinationscluster [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′‐bis(2,6‐diisopropylphenyl)‐formamidinat). Dies sind die ersten f‐Element‐Koordinationscluster (LnnSx) mit einer größeren Polysulfideinheit (n und x>2). Die Bildung dieser Spezies kann über die...
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