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Chiral polyether-phosphite ligands derived from (S)-binaphtol were prepared and combined with [Rh(cod) 2 ]BF 4 complex. These systems showed high activity, chemo- and regioselectivity, for the catalytic enantioselective hydroformylation of styrene in thermoregulated phase-transfer conditions. ee Values of up to 25% were obtained and recycling was possible, without loss of enantioselectivity...
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