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A novel functionalized norbornene-based copolymer with long poly(ɛ-caprolactone) side chain and cyano group was synthesized in the combination of ring-opening polymerization and ring-opening metathesis polymerization, which was characterized by means of 1 H NMR, gel permeation chromatography, thermogravimetry, differential scanning calorimetry, wide-angle X-ray diffraction, and stress–strain...
A combination of ring-opening metathesis polymerization (ROMP) and click chemistry approach was utilized for the first time in preparation of multiblock copolymers. The dibromo-functionalized telechelic poly(butadiene) (PBD) was synthesized firstly by ROMP of 1,5-cyclooctadiene in the presence of a symmetrical difunctional chain transfer agent and transformed into diazido-telechelic PBD, which was...
A new amphiphilic AB 2 star copolymer was synthesized by the combination of ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP). Two different routes (methods A and B) were employed firstly to prepare the poly(oxanorbornene)-based monotelechelic polymers as the hydrophobic arm bearing dibromo-ended group via ROMP in the presence of two different terminating...
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