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The reactions of CpFe(dppe)I with thiophenes in the presence of TIPF 6 afforded the new complexes [CpFe(dppe)thiophenes]PF 6 (thiophenes = thiophene, 2-methyl-thiophene, 3-methyl-thiophene, 2,5-dimethyl-thiophene, benzothiophene and dibenzothiophene). They were characterized by elemental analysis, IR, 1 H, 31 P and 13 C NMR as well as by UV-visible...
Trans-[BrMn(CO) 2 (dppm)P(OPh) 3 ] reacts with SR 2 ; R = C 2 H 5 and C 3 H 7 to give the cationic complexes trans-[Mn(CO) 2 (dppm)P(OPh) 3 (SR 2 )]PF 6 while from the reaction of cis,cis-[BrMn(CO) 2 (dppm)P(OPh) 3 ] with the thioether ligands the unaltered dicarbonyl manganese complex was isolated...
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