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We have investigated the electronic structure of La1-xPrxCoO3 and NdCoO3 studied by photoemission spectroscopy at 200K using several photon energies over the Pr or Nd 4d–4f resonance. All the spectra except near the 4d–4f on-resonance displayed a distinct sharp peak at ∼1eV due to the Co 3d6 low-spin (LS) and/or intermediate-spin (IS) state. This 1-eV peak in PrCoO3 and NdCoO3 was substantially narrower...
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