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An oligomer of a diepoxy (diglycidyl ether of bisphenol-A, DGEBA) and an aromatic diamine (MCDEA) have been used as reactive plasticizers for polycarbonate (PC). A small amount of PC chain scission occurred during this blending process, probably due to transesterification of the PC carbonate group by the hydroxyl group of the DGEBA oligomer. Addition of DGEBA to PC was found to greatly reduce the...
Diallyl orthophthalate (DAOP) has been used as a reactive plasticizer for polycarbonate (PC) due to the low reactivity and high conversion at the gel point of DAOP and its high solubility in PC. Miscible blends of PC with various ratios of DAOP have been investigated using gel permeation chromatography, differential scanning calorimetry, rheometry, dynamic mechanical thermal analysis and optical microscopy...
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