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Graft copolymers of natural rubber and maleic anhydride (NR-g-MA) or maleated natural rubber (MNR) were synthesized in a toluene solution. Benzoyl peroxide (BPO) was used to initiate the free radical graft copolymerization. Influence of monomer and initiator concentrations together with effect of the reaction temperature and reaction time were investigated. Quantities of the grafted anhydride (MA)...
Two types of natural rubber (ADS and STR 5L) were used to prepare maleated natural rubber (MNR). Melt rheological properties of MNRs (i.e. MNR-ADS and MNR-STR) and their blends with the same type of natural rubber were quantified. We found that the Mooney viscosities of MNR-ADS/ADS blends were higher than those of MNR-STR/STR 5L blends. The log additive rule was applied to the Mooney viscosity data...
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