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Hydrogenation of cyclohexanone was studied over Pt(111) and two ordered, Pt-Sn alloy surfaces formed by vapor deposition of Sn on the Pt(111) single crystal surface-the (2x2) Sn/Pt(111) and (3x3)R30 o Sn/Pt(111) surface alloys. The influence of alloying Sn, alloy structure, partial pressures of hydrogen and cyclohexanone, and temperature on the activity and selectivity of these model catalysts...
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