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Hydrogels of N-vinylimidazole are polymerized in molds of different materials (acidic glass, basic glass, silanized glass, nylon, Teflon, pvc) to study the influence of the material on the gel properties. Molds are cylinders of very narrow diameter (2–8mm) to enhance the influence of the wall. Confocal microscopy, glass transition, and degree of swelling are used to characterize the gels. A border...
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