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•We measured and calculated electrophoretic mobility of carboxyl latex particles in mixed solution of KCl and CaCl2 or KCl and LaCl3.•Used theoretical models consider the deprotonation, the binding of Ca2+/La3+, diffuse double layer model, and the double layer relaxation. Experimental data are reasonably described by the theoretical models except the case with La3+ at high pH.•The surface charge reduces...
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