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Halogen‐bond mediated 3D confined assembly gives rise to a profound picture of morphological transition when combining with polymer donor‐acceptor pairs, changing from spherical to cylindrical, lamellar, and then to inverse cylindrical structures, by tuning the feeding ratio and choice of surfactant (presented by Senbin Chen, Wolfgang H. Binder, Jintao Zhu, and co‐workers in article number 2007570)...
Halogen‐bond driven assembly, a world parallel to hydrogen‐bond, has emerged as an attractive tool for constructing (macro)molecular arrangement. However, knowledge about halogen‐bond mediated confined‐assembly in emulsion droplets is limited so far. An I….N bond mediated confined‐assembly pathway to enable order‐order phase transitions is reported here. Compared to hydrogen bonds, the distinct features...
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