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Hydrogen peroxide is involved in a variety of enzyme catalysis as an oxidant or toxic by‐product. Thereby, attenuation of the H2O2‐driven oxidative stress is one of the key issues for preparative biocatalysis. Here, a rational approach to improve the robustness of enzymes, in particular, Baeyer‐Villiger monooxygenases (BVMOs) against H2O2 was investigated. The enzyme access tunnels, which may serve...
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