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Reaction of the sterically bulky 1,3-dibenzhydrylbenzimidazolium bromide (Bh 2 -bimyH + Br − ) (A) with Pd(OAc) 2 in DMSO yielded a mono(carbene) Pd(II) complex 1 with a N-bound benzimidazole derivative, which resulted from an unusual NHC rearrangement reaction. Reaction of A with Ag 2 O, on the other hand, cleanly gave the Ag(I) carbene complex [AgBr(Bh ...
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